Citation: Zhong Ning CHEN, Zhong Gui WU, Wen Xia TANG, Kai Bei YU. SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST THREE DIMENSIONAL NETWORK CU(Ⅱ) COMPLEX BRIDGED BY BOTH OXAMIDE AND AZIDE[J]. Chinese Chemical Letters, ;1993, 4(11): 1029-1030. shu

SYNTHESIS AND CRYSTAL STRUCTURE OF THE FIRST THREE DIMENSIONAL NETWORK CU(Ⅱ) COMPLEX BRIDGED BY BOTH OXAMIDE AND AZIDE

a State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008;
b Analysis Center, Chengdu Branch of Chinese Academy of Science, Chengdu 610041

Received Date: 16 July 1993

A novel three dimensional network complex polymer[Cu₄ (oxen)₂(N₃)₃]_{n_{(ClO₄)_n·2nH₂O, where oxen is N, N'-bis(2-aminoethyl) oxamide dianion, has been synthesized. It crystallizes in triclinic system, space group P1, with a=11.486 (2), b=11.706 (3), c=12.291 (3)Å, α=77.42 (2), β=67.59 (2), γ=77.96 (2)°, and z=2. The least-square refinements converged at R=0.047, with 3416 observed unique reflections. The complex has a pronounced three-dimensional character and can be viewed as the tetranuclear asymmetric repeating units through inversion and translation operations to extend a three-dimensional network. The structure of Cu₄ asymmetric unit consists of two square planar and two square pyramidal Cu central atoms linked by both azide ligands in end-on and end-to-end bonding modes, and oxamidate bridge in trans conformation.}}
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