Citation: Yue Zhi CUI, Qi FANG, Hong LEI, Gang XUE, Wen Tao YU. The Structure and Nonlinear Optical Properties of Octupolar Compound:2,4,6-Tristyryl-s-triazine[J]. Chinese Chemical Letters, ;2003, 14(8): 856-859. shu

The Structure and Nonlinear Optical Properties of Octupolar Compound:2,4,6-Tristyryl-s-triazine

Yue Zhi CUI ^1, ,
Qi FANG ¹ ,
Hong LEI ² ,
Gang XUE ¹ ,
Wen Tao YU ¹

1.
State Kay Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
School of Information Science and Engineering, Shandong University, Jinan 250100

Received Date: 27 August 2002

Fund Project: This work was supported by the National Natural Science Foundation of China (No.20172034), Foundation for University Key Teacher by Ministry of Education, and the grant for state key program of China.

The crystal of 2,4,6-tristyryl-s-triazine (TSTA) has been prepared and its crystal structure been determined to be in the polar non-centrosymmetric space group Cmc2₁. The molecular structure of TSTA is characterized by the slightly curved planar configuration and the octupolar C_3v molecular symmetry. As expected, TSTA crystal shows a quite novel nonlinear optical (NLO) property with its powder second harmonic generating (SHG) intensity of 1.8 times as that of urea. It also shows excellent transparency (with the peak position of 322 nm in absorption spectrum) and good thermal stability (with the melting point of 225-229℃).
- TSTA,
- crystal structure,
- SHG
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