Citation: Xiang Dong JIAO, Jin Wang HUANG, Jun Fen LIU, Ling Nian JI. EVIDENCE FOR THE NOVEL COORDINATION MODE OF TERMINAL GROUP OF SOME TAILED PORPHYRIN IRON(Ⅱ) COMPLEXES[J]. Chinese Chemical Letters, ;1994, 5(7): 615-616. shu

EVIDENCE FOR THE NOVEL COORDINATION MODE OF TERMINAL GROUP OF SOME TAILED PORPHYRIN IRON(Ⅱ) COMPLEXES

Department of Chemistry, Zhongshan University,, Guangzhou, 510275/National KeyLaboratory of Applied Organic Chemistry at Lanzhou University, Lanzhou, 730000

Received Date: 22 April 1994

EPR spectra were measured at 77K for two tailed porphyrin iron(Ⅲ) complexee,5-[o-(1-imidazolyl)butaxyl]phenyl-10,15,20-triphenylporphyrinatairon(Ⅲ) chloride[Mo-ImBPTPPFe(Ⅲ)Cl]and δ-[p-[4-(m-pyridyloxy)butoxyl]phenyl]-10,16,20-triphenylporphyrinatoiron(Ⅲ)chloride[p-PyBPTPPFe(Ⅲ)Cl,and their adducts with imidazole or pyridine,the crystal field parameters of these adducts were calculated from g values.The ¹H NMB and visible spectra of these adducts are compared with each other.Form these data,the novel coordination mode of terminal imidaxole in o-ImBPTPPFe(Ⅲ)Cl system were identified.
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