Citation: Shou Gang WANG, Hong Wei XIANG, Bu Xing HAN. A New Perturbed Hard-Sphere Equation of State[J]. Chinese Chemical Letters, ;2000, 11(11): 989-992. shu

A New Perturbed Hard-Sphere Equation of State

Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received Date: 15 May 2000

Fund Project: The authors are grateful to the National Natural Science Foundation of China and Chinese Academy of Sciences for financial support (29725308, 29633020).

A new equation of state based on hard-sphere perturbed theory was developed. This equation combined the CS repulsive term and Guo-Du attractive term. Parameters of 38 substances were estimated, the pressure-volume-temperature properties were calculated and compared with two other equations. The results show that this equation is more accurate.
- Equation of state,
- hard-sphereperturbed theory,
- thermodynamic properties
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