Citation: Hong Zhu MA, Bo WANG. Asymmetric Hydrogenation Synthesis of (S)-(+)-2-(6'-methoxyl-2-naphthyl) propionic Acid by Cinchona Modified Pd(0)-α-FeOOH Catalyst[J]. Chinese Chemical Letters, ;2003, 14(11): 1101-1104. shu

Asymmetric Hydrogenation Synthesis of (S)-(+)-2-(6'-methoxyl-2-naphthyl) propionic Acid by Cinchona Modified Pd(0)-α-FeOOH Catalyst

Hong Zhu MA ,
Bo WANG

Chemistry and materials science, ShanXi Normal University, Xi'an 710062

Received Date: 16 September 2002

Asymmetric hydrogenation of (6-methoxyl-2-naphthyl)-2-acrylic acid catalyzed by cinchona modified Pd(0)-α-FeOOH was reported and ee's of (S)-(+)-2-(6'-methoxyl-2-naphthyl) propionic acid ((S)-(+)-naproxen) up to 98% was achieved firstly.
- Asymmetric hydrogenation,
- catalyze,
- cinchona,
- Pd(0)-α-FeOOH,
- (S)-(+)-naproxen
1. [1]
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2. [2]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
3. [3]
  Xiaoxiao Huang , Zhi-Long He , Yangpeng Chen , Lei Li , Zhenyu Yang , Chunyang Zhai , Mingshan Zhu . Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation. Chinese Chemical Letters, 2024, 35(6): 109271-. doi: 10.1016/j.cclet.2023.109271
4. [4]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
5. [5]
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7. [7]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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