Citation: . THE Θ-STATE OF A SINGLE HOMOPOLYMER CHAIN IN SOLUTION*[J]. Chinese Journal of Polymer Science, ;1999, 17(4): 367-370. shu

THE Θ-STATE OF A SINGLE HOMOPOLYMER CHAIN IN SOLUTION*

Received Date: 11 December 1998

It has been an established practice to estimate the Θ-temperature of a polymer solution from thedisappearance of the interchain interactions (A2 = 0) Recently, in studies of the temperature dependence ofthe chain conformation in solution, we found that the change of the chain conformation clearly underwentthree different stages which could be viewed as the "gas". "liquid" and "solid" states in terms of the freedomof the "blobs" on the chain. The transition temperature between the first and second stages corresponds nicely to the Θ-temperature determined by the conventional method.It reveals,for the first time,that the Θ-temperature can be deduced from the conformation change of a single polymer chain in solution,which is important not only in conception,but also in practice.
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