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Citation: Li Guangxing, Liu Yong. Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation[J]. Chinese Journal of Applied Chemistry, ;1998, 15(1): 116-118. shu

Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation

Li Guangxing ,
Liu Yong

Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received Date: 10 July 1997
Revised Date: 6 October 1997

Sodium tetracarbonyl cobaltate was prepared by reaction of CO with CoCl₂ in CH₃OH, using Urushibara-Cobalt (U-Co) as activator and characterized by IR spectrometry. The optimum conditions were: Co(from U-Co)/CoCl₂=0.6; 30 ℃; 0.1 MPa of CO. The convertion of CoCl₂ in 3 h of reaction was 96%. The convertion of benzyl chloride to pheny-lacetic acid using the Na[Co(CO)₄] as catalyst was about 90% at 50℃ and 0.1 MPa of CO.
- sodium tetracarbonyl cobaltate,
- urushibara-cobalt,
- phenylacetic acid,
- synthesis
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Synthesis of Sodium Tetracarbonylcobaltate Using Urushibara-Co/CH₃OH/CoCl₂/CO and Its Application in Carbonylation