Citation: Shu Jia LI, Heng Bin ZHANG, Shu Yun NIU, Guang Di YANG, Fu NIE. SYNTHESIS AND STRUCTURE OF A MIXED-VALENCE HEXAMOLYBDENUM COMPLEX [Et₄N]₂[Mo₆O₁₉H₄][J]. Chinese Chemical Letters, ;1992, 3(6): 459-462. shu

SYNTHESIS AND STRUCTURE OF A MIXED-VALENCE HEXAMOLYBDENUM COMPLEX [Et₄N]₂[Mo₆O₁₉H₄]

a Department of Chemistry Jilin University Changchun 130023;
b Institute of Theoretic Chemistry Jilin University Changchun 130023

Received Date: 16 January 1992

A hexamolybdenum complex, [Et₄N]₂[Mo₆O₁₉H₄] crystal, withpentavalent and hexavalent molybdenum has been obtained in the solution ofDMF and CH₃OH as organic solvents using MoCl₅ as a starting material.Thecrystallographic parameters obtained by X-ray diffraction analysis are:crthorhombic, a=10.757(3), b=10.763(2), c=14.238(4)Å, =1648.9Å₃; Z=2; spacegroup Pnnm; final R=0.047; final Rw=0.051**
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