Citation: Lian Bin LI, Xiang Hong LIU, Xiu Yan WANG. The Formation of the Cluster Ions NH₅⁺ and (NH₃)₂H₂⁺ and ab initio Calculation Study of Their Structures[J]. Chinese Chemical Letters, ;1999, 10(4): 312-324. shu

The Formation of the Cluster Ions NH₅⁺ and (NH₃)₂H₂⁺ and ab initio Calculation Study of Their Structures

State key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 16023

Received Date: 17 November 1998

The mass spectra of cluster ions (NH₃)_nH₂⁺ with n<4 were measured for the first time using a MPI mass spectrometer. The structures of the cluster ions NH₅⁺ and (NH₃)₂H₂⁺ were calculated using GAUSSIAN-94 package, and stable structures for both of them were found.
- Ammonia,
- cluster,
- multiphoton ionization,
- proton transfer,
- ab inition calculation
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