Citation: YU Qingsong, YE Mu, LU Lizhen, CHEN Jie, WANG Fosong, Yoshihito Osada. A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE[J]. Chinese Journal of Polymer Science, ;1988, 6(2): 172-177. shu

A STUDY OF THE POLYMERIZATION MECHANISM OF ACETONITRILE IN GLOW DISCHARGE

Received Date: 7 April 1987

Plasma polymerization of acetonitrile was carried out by a capacitively coupled RF plasma apparatus with external electrodes under some different reaction conditions such as discharge power. By investigating the informations provided by the polymer deposition regularities, IR spectra and elementary analysis results, the polymerization mechanism of acetonitrile in glow discharge have been investigated. The results show that acetonitrile polymerized in glow discharge mainly through hydrogen detachment for initiation at lower energy levels and the role that opening C=N triple bond played in polymerization became more important at higher energy levels.
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