Citation: Zhao Ming XUE, Yu Peng TIAN, Dong WANG, Min Hua JIANG. One-and Two-photon Excited Fluorescence of Zinc(Ⅱ), Cadmium(Ⅱ) Complexes Containing Phenothiazine Ligand[J]. Chinese Chemical Letters, ;2003, 14(5): 525-528. shu

One-and Two-photon Excited Fluorescence of Zinc(Ⅱ), Cadmium(Ⅱ) Complexes Containing Phenothiazine Ligand

1.
Department of Chemistry, Anhui University, Hefei 230039;
2.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100

Received Date: 25 July 2002

Fund Project: This work was supported by the grant for the State Key Program of China (G1998061402), and the National Natural Science Foundation of China (29871001, 20071001).

A new ligand, 10-ethylphenothiazinyl-3-yl-methylene thiosemicarbazon (HL) and its complexes ML₂(M=Zn²⁺, Cd²⁺), which exhibit intensive two-photon excited (TPE) fluorescence at 800 nm laser pulses in femtosecond regime, were synthesized and characterized.The measured power dependence of the fluorescence signals provided direct evidence for TPE.All of them exhibited a large two-photon absorptive cross section and, more importantly from the application point of view, high photochemical/photothermal stability.
- OPE,
- TPE,
- complex,
- phenothiazine
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