Citation: Xin CHEN, Yu Ping FENG, Nan Jing ZHANG, Yu Fen ZHAO. STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES[J]. Chinese Chemical Letters, ;1995, 6(7): 577-580. shu

STRUCTURE ASSIGNMENT FOR EPIMERIC THYMIDINE-3'-YL BENZOIN PHOSPHATES

Bio-organic Phosphorus Chemistry Laboratory, Department of Chemistry Tsinghua University, Beijing 100084

Received Date: 12 January 1995

Fund Project: The financial supports from National Natural Science Foundation of China are greatly appreciated.

Reaction of oxyphosphorane (1) with thymidine (2) followed by hydrolysis under mild conditions afforded TMP, TpT and thymidine-3'-yl benzoin phosphates (3).The structures of 3 were determined by ³¹P, ¹H, ¹³C NMR and mass spectral data, and ³¹P-¹H COSY experiments.The possible formation mechanism of 3 was also discussed.
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