Citation: TIAN Ju-Mei, CUI Zheng, ZHANG Jing-Ping. Syntheses and Structures Characterization of a Family of Hexanuclear Iron(Ⅲ) Clusters[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1625-1630. shu

Syntheses and Structures Characterization of a Family of Hexanuclear Iron(Ⅲ) Clusters

1.
Department of Stomatology, Xiamen Medical College, Xiamen, Fujian 361023, China
2.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: TIAN Ju-Mei, tjm@xmmc.edu.cn
Received Date: 4 March 2017
Revised Date: 8 July 2017

Figures(4)

Solvothermal reactions of 1, 1, 1-tris(hydroxymethyl)propane (H₃tmp) and FeCl₃ by using different counter ions resulted in three hexanuclear iron(Ⅲ)clusters (C₅N₂H₁₄)[Fe₆(μ₆-O)Cl₆(tmp)₄]·2H₂O·CH₃OH (1), (C₃N₂H₅)₂[Fe₆(μ₆-O)Cl₆(tmp)₄] (2), and (C₄N₃H₈)₃(C₂N₃H₄)[Fe₁₂(μ₆-O)₂Cl₁₂(tmp)₈]·3CH₃OH (3), whose structures were characterized. The tripodal alcohols ligands are very useful in constructing high-nuclearity metal clusters. In all cases, similar anionic cluster[Fe₆(μ₆-O)Cl₆(tmp)₄]^2- is formed by six Fe(Ⅲ)ions, four tmp^3- ligands, one center O^2- ion, and six Cl^- ions. Within the system of compounds 1 and 3, the nitrogen-containing heterocyclic ligands experience N-and C-alkylation reactions, which is validated by the crystallographic parameters, elemental analyses, and IR. CCDC: 980726, 1; 980727, 2; 980728, 3.
- hexanuclear iron (Ⅲ) clusters,
- crystal structure,
- counter ions
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沈阳化工大学材料科学与工程学院沈阳 110142