Citation: Li Ming TANG, Dan WU, Mei Yu HUANG, Ying Yan JIANG. CATALYTIC PROPERTIES OF SILICA-SUPPORTED POLY-γ-AMINOPROPYLSILOXANE-RHODIUM-COBALT BIMETALLIC COMPLEX FOR HYDROFORMYLATION[J]. Chinese Chemical Letters, ;1994, 5(6): 531-532. shu

CATALYTIC PROPERTIES OF SILICA-SUPPORTED POLY-γ-AMINOPROPYLSILOXANE-RHODIUM-COBALT BIMETALLIC COMPLEX FOR HYDROFORMYLATION

Institute of Chemistry, Academia Sinica, Beijing 100080

Received Date: 7 March 1994

Hydroformylation of methyl methacrylate with a conversion of 95.6% and selectivity of 92.8% for the normal product,methyl β-formylisobutyrate has been achieved when the reaction was catalyzed by a silica-supported poly-γ-aminopropylsiloxane-rhodium-cobalt bimetallic complex (abbreviated as SiO₂-NH₂-Rh-Co).The catalyst was stable during the reaction and could be used repeatedly.
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