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Citation: Dai Jinshui. Phase-transfer-catalytic Synthesis of 1-Naphthalene Acetic Acid by Octacarbonyl Dicobalt[J]. Chinese Journal of Applied Chemistry, ;1998, 15(1): 86-88. shu

Phase-transfer-catalytic Synthesis of 1-Naphthalene Acetic Acid by Octacarbonyl Dicobalt

Dai Jinshui

The 12th Teaching Office, Institute of Chemical Defence, Beijing 102205

Received Date: 16 June 1997
Revised Date: 26 September 1997

1-Naphthalene acetic acid was synthesized from 1-chloromethyl naphthalene by octacarbonyl dicobalt under phase transfer catalytic conditions. Conversion was 99% and yield 83%. The effects of reaction temperatures, ratios of reactants, solvents, contents of catalyst and concentration of alkali on conversion have been investigated. Among the phase transfer catalysts tested, the most effective was hexadecyltrimethylammonium chloride.
- naphthaleneacetic acid,
- synthesis,
- chloromethyl naphthalene,
- phase transfer catalysis,
- octacarbonyl cobalt
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