Citation: Ying LIU, Guo Sheng DING, Jun De WANG. Recognition Interactions of Metal-complexing Imprinted Polymer[J]. Chinese Chemical Letters, ;2005, 16(6): 797-800. shu

Recognition Interactions of Metal-complexing Imprinted Polymer

Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012

Received Date: 8 June 2004

Molecularly imprinted polymer, exhibiting considerable enantioselectivity for L-mandelic acid, was prepared using metal coordination-chelation interaction. By evaluating the recognition characteristics in the chromatographic mode, the recognition interactions were proposed:specific and nonspecific metal coordination-chelation interaction and hydrophobic interaction were responsible for substrate binding on metal-complexing imprinted polymer; while the selective recognition only came from specific metal coordination-chelation interaction and specific hydrophobic interaction.
- Molecularly imprinted polymer,
- metal coordination-chelation interaction,
- recognition interaction,
- enantioseparation
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