Citation: Jun Fa WEI, Xian Da YU, Dao Sen JIN. A Methane Monooxygenase-like DinuclearIron (Ⅲ) Complex and its Catalytic Ability for Asymmetric Epoxidation of Styrene[J]. Chinese Chemical Letters, ;1996, 7(10): 962-964. shu

A Methane Monooxygenase-like DinuclearIron (Ⅲ) Complex and its Catalytic Ability for Asymmetric Epoxidation of Styrene

Lanzhou Institute of Chemical Physics Academia Sinica Lanzhou 730000

Received Date: 22 April 1996

A methane monooxygenase-like dinuclear complex of iron (Ⅲ) with a chiral heptadentate ligand has been synthesed and tested for catalytic ability for asymmetric epoxidation of styrene with iodosylbenzene.The results show that the complex exhibits many qualitative features, such as electronic spectrum, catalytic behavior, and asymmetric induction similar to those of methane monooxygenase and catalyzes styrene epoxidation to R-(+)-styrene oxide in 9.3% yield and 72.9% optical yield.
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