Citation: Wei DENG, Ye Feng WANG, Chen ZHANG, Lei LIU, Qing Xiang GUO. CuI/Proline-catalyzed N-Arylation of Nitrogen Heterocycles[J]. Chinese Chemical Letters, ;2006, 17(3): 313-316. shu

CuI/Proline-catalyzed N-Arylation of Nitrogen Heterocycles

Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received Date: 27 June 2005

Fund Project: This research was supported by the NNSFC (No.20332020, 20472079).

Ma's CuI/proline procedure for the catalytic cross coupling between nitrogen heterocycles and aryl halides was markedly improved. The key finding was that K₃PO₄ was a much better base than K₂CO₃ for the reaction. With this new reaction condition the cross coupling with aryl iodides could be accomplished in 1, 4-dioxane instead of DMSO. This reactin also could be carried out in DMF. Furthermore, the coupling yields under the new conditions are usually higher than in Ma's original methods.
- Cross coupling reaction,
- CuI,
- N-arylation,
- nitrogen heterocycle,
- proline
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