Citation: Er Chang LIU, Ding Qiao YANG, Ying Feng HAN, Jian Xia DONG. The Studies of Rhodium-catalyzed Ring Opening Reaction of N-Boc azabenzonorbornadiene with Heteroatom Nucleophiles[J]. Chinese Chemical Letters, ;2006, 17(6): 717-719. shu

The Studies of Rhodium-catalyzed Ring Opening Reaction of N-Boc azabenzonorbornadiene with Heteroatom Nucleophiles

School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received Date: 18 July 2005

Fund Project: We would like to thank the Natural Science Fundation Council of Guangdong Province (No. 04010404) and the Analysis and Test Center of the South China Normal University.

A rhodium-catalyzed ring opening reaction of N-Boc-azabenzonorbornadiene with heteroatom nucleophiles was described. Piperidine and piperazine's derivatives were nucleophiles in this reaction. The yields of the products 2a-f are good and the regioselectivity are excellent.
- Rhodium-catalyzed,
- N-Boc-azabenzonorbomadiene,
- nucleophiles,
- ring opening
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