Citation: Wen Ming ZHANG, Li ZHANG, Shi Jian LIAO, Yun XU, Dao Rong YU. CYCLOTRIMERIZATION OF NITRILES BY THE REACTIVE ALKALI METAL HYDRIDES[J]. Chinese Chemical Letters, ;1995, 6(10): 839-842. shu

CYCLOTRIMERIZATION OF NITRILES BY THE REACTIVE ALKALI METAL HYDRIDES

Wen Ming ZHANG ^1,2 ,
Li ZHANG ^1,2 ,
Shi Jian LIAO ^1,2 ,
Yun XU ^1,2 ,
Dao Rong YU ^1,2

1.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;
2.
Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 4 April 1995

Fund Project: This work was supported by the National Natural Science Foundation of China.

In the presence of reactive alkali metal hydrides,nitriles can be cyclotrimerized to give 2,4,6-trisubstituted-1,3,5-triazines and 2,4,6-trisubstituted imidazoles in moderate yield.
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