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Citation: Li Shufang. On the Structure and Catalytic Property of Sn_0.8Mo_0.2 Mixed Oxide[J]. Chinese Journal of Applied Chemistry, ;1998, 15(4): 59-61. shu

On the Structure and Catalytic Property of Sn_0.8Mo_0.2 Mixed Oxide

Li Shufang

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 8 December 1997
Revised Date: 21 May 1998

The correlation between the catalytic activity and structure of Sn_0.8Mo_0.2 mixed oxides calcinated at diffrent temperatures has been investigated by using ESR, XPS and XRD techniques. The results show that at 100~300 ℃ molybdenum disperses on the surface of rutile-type stannic oxide formed at 100℃, at 300~500℃ it gradually diffuses into SnO₂ and at 550℃ the interstitial solid solution forms, which exhibites the best catalytic activity in oxidation of butene. The substitution solid solution forms at 600℃.
- Mo-Sn mixed oxide,
- structure,
- catalytic property,
- butene,
- oxidation
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通讯作者: 陈斌, bchen63@163.com

On the Structure and Catalytic Property of Sn_0.8Mo_0.2 Mixed Oxide