Citation: Yan Xing JIA, Bin WU, Ping Zhen WANG, Yong Qiang TU. Synthetic Studies of Didemnaketals Analogue-Construction of the Intermediate (3S,5S,6R)-3,7-Dimethyl-5,6,7-trihydroxy-octanal[J]. Chinese Chemical Letters, ;2000, 11(6): 509-510. shu

Synthetic Studies of Didemnaketals Analogue-Construction of the Intermediate (3S,5S,6R)-3,7-Dimethyl-5,6,7-trihydroxy-octanal

Department of Chemistry and National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 21 January 2000

Fund Project: We are grateful for financial support of a NSFC(29925205) and the Education Council of China.

An efficient and stereoselective synthetic procedure for (3S,5S,6R)-3,7-dimethyl-5,6,7-trihydroxy-octanal derivative, the intermediate for synthetic of the HIV-active didemnaketals analogue, was developed via a series of reactions from the natural (+)-Pulegone. In this approach, an efficient diastereoselective reaction of the epoxides 8 and 9 with PCC has been accomplished.
- Didemnaketals,
- stereoselective synthesis,
- diastereoselective reaction
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