Citation: Xiao CHEN, Yong Xin ZHANG, Da Ming DU, Wen Ting HUA. New Chiral Pyridine Prolinol Derivatives and Preliminary Study on Asymmetric Catalytic Reaction[J]. Chinese Chemical Letters, ;2004, 15(2): 167-168. shu

New Chiral Pyridine Prolinol Derivatives and Preliminary Study on Asymmetric Catalytic Reaction

1.
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871;
2.
Shangqiu normal University, Shangqiu 476000

Received Date: 11 February 2003

Fund Project: Project supported by the National Natural Science Foundation of China (Grant No. 20172001).

Two new chiral pyridine prolinol derivatives have been synthesized from N-alkylation of (S)-α, α-diphenyl-2-pyrrolidinemethanol with 2-bromomethylpyridine and 2, 6-dibromo-methyl-pyridine. The catalytic asymmetric borane reduction of prochiral ketones and the asymmetric addition of diethylzinc to benzaldehyde were investigated.
- Prolinol,
- pyridine,
- enantioselective reaction,
- borane
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