Citation: . POLYMERIZATION OF A NEW SUBSTITUTED ACETYLENE BEARING A FURAN RING WITH PALLADIUM ACETYLIDE CATALYSTS*[J]. Chinese Journal of Polymer Science, ;2004, 22(5): 485-490.
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A substituted polyacetylene bearing a furan ring, poly(2-propynyl 2-furoate) (PPF), was synthesized for the first time with palladium acetylide complex catalysts in CHCl3 at 60°C to give a soluble and stable polymer with a yield of ca.75%. Some features for polymerization of 2-propynyl 2-furoate are described and discussed. The resulting polymer was characterized by IR, GPC and 1H-NMR analysis.
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