Citation: Yong LUO, Lan LIU, Li Hong LI, Qin Ying DENG. Preparation of High Selective Molecularly Imprinted Polymers for (S)-4-Phenyl-2-oxazolidinone[J]. Chinese Chemical Letters, ;2006, 17(12): 1551-1554. shu

Preparation of High Selective Molecularly Imprinted Polymers for (S)-4-Phenyl-2-oxazolidinone

School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275

Received Date: 7 September 2006

Fund Project: This work was financed by the National Natural Science Foundation of China (No. 20202015).

(S)-4-Phenyl-2-oxazolidinone imprinted polymers were prepared by using methacrylic acid (MAA) as the functional monomer, and divinylbenzene (DVB) as crosslinker. The factors, which influence the selectivity of the polymers were explored. Effective separation was observed for racemic 4-phenyl-2-oxazolidinone in mobile phase of acetonitrile. The investigation of mobile phase suggested that the hydrogen bonds between template and functional monomer was a primary factor in chiral recognition, while the preparation of polymers implied that the π-π stacking interaction between template and crosslinker played a role in imprinting procedure.
- Molecularly imprinted polymers (MIPs),
- 4-phenyl-2-oxazolidinone,
- HPLC
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