Citation: Zao Ying LI, Xun Jin ZHU, Li LI, Yue Ning ZHANG. Synthesis of Glucoside Bonded Metal Porphyrins[J]. Chinese Chemical Letters, ;2001, 12(5): 425-428. shu

Synthesis of Glucoside Bonded Metal Porphyrins

Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 20 October 2000

Fund Project: This work was supported by the National Natural Science Foundation of China (projects No. 29972035).

The reactions of 5,10,15,20-tetrakis (p-hydroxyphenyl) porphyrin 1 and 5-(p-hydroxy-phenyl)-10,15,20-tris (p-methoxyphenyl) porphyrin 2 with 1-bromo-2,3,4,6-O-acetyl-α-D-glu-coside 3 respectively afforded 5,10,15,20-tetrakis [p-(2,3,4,6-O-acetyl-glucoside)-1-O-phenyl] porphyrin 4 and 5,10,15-tris (p-methoxyphenyl)-20-[p-(2,3,4,6-O-acetyl-glucoside)-1-O-phenyl] porphyrin 5.Their metal complexes Co^Ⅱ (4),Mn^Ⅱ (4) and Co^Ⅱ (5),Mn^Ⅱ (5) also have been prepared.These new compounds have been identified by IR,UV-visible,¹H NMR spectra and elemental analysis.
- Glucoside,
- metalloporphyrin,
- synthesis.
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