Citation: liang Fu HUANG, Bao Ming XU, Shu Xiang SHAN, Xue You ZHU. A CONVENIENT APPROACH OF DIYNE ALCOHOL AND TRIYNE ALCOHOL BY COPPER (Ⅰ) AND PHASE TRANSFER CONDITION CATALYZED PROPARGYLATION OF PROPARGYL ALCOHOL[J]. Chinese Chemical Letters, ;1993, 4(1): 13-16. shu

A CONVENIENT APPROACH OF DIYNE ALCOHOL AND TRIYNE ALCOHOL BY COPPER (Ⅰ) AND PHASE TRANSFER CONDITION CATALYZED PROPARGYLATION OF PROPARGYL ALCOHOL

1.
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences 345 Llngling Lu, Shanghai 200032;
2.
Department of Biotechnology, Sichuan University, Chengdu 610064

Received Date: 11 June 1992

Fund Project: This investigation was supported by the Youth Fund of Sichuan University. We are grateful to Prof. Wei-Shan ZHOU for useful criticism. We also thank Prof, Hua-Yi LIU, Prof. Wan-Hui DENG and Dr. Ping LI for Mass spectra and IR spectra analysis.

The copper(Ⅰ) catalyzed coupling reaction of substituted propargyl tosylate with propargyl alcohol proceeds smoothly at room temperature to give 2,5-diynyl alcohol under solid-liquid phase transfer condition. A number of 2,5-diynyl alcohols and 2,5,8-triynyl alcohols were synthesized in this way in good yield.
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