Citation: Jing Lin CHEN, Gang Qiang YIN, Zhong Ning CHEN. Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru₃^ш(μ₃-O)(μ-CH₃COO)₆(py)₂Cl with Four Steps One-electron Redox Processes[J]. Chinese Chemical Letters, ;2003, 14(5): 519-522. shu

Synthesis, X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru₃^ш(μ₃-O)(μ-CH₃COO)₆(py)₂Cl with Four Steps One-electron Redox Processes

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002

Received Date: 4 July 2002

Fund Project: This work was financially supported by the National Natural Science Foundations of China (No. 20171044 and 20273074) and Chinese Academy of Sciences for "hundred talents".

The synthesis and crystal structure of oxo-centered carboxylate-bridge trinuclear ruthenium complex, Ru₃O(CH₃COO)₆(py)₂Cl (py =pyridine) (1), are reported herein.The complex 1 has been characterized by IR, cyclic voltammetry (CV), UV-Vis and X-ray crystal analysis.The complex 1 in 0.1 mol/L (n-C₄H₉)₄NPF₆-CH₂Cl₂ solution at room temperature shows four one-electron redox processes at E_1/2=-1.38,-1.20,-0.17 and 1.07 V vs.Ag/AgCl.
- Crystal structure,
- ruthenium,
- carboxylate,
- electrochemistry
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