Citation: Zheng Wu WANG, Gan Zuo LI, Da Ren GUAN, Xi Zhang YI, An Jing LOU. Study of the Electrical Double Layer of a Spherical Micelle:Functional Theoretical Approach[J]. Chinese Chemical Letters, ;2001, 12(7): 645-646. shu

Study of the Electrical Double Layer of a Spherical Micelle:Functional Theoretical Approach

1.
Key Lab of Colloid and Interface Chemistry for State Education Ministry, Shandong University, Ji'nan 250100;
2.
Institute of Theoretical Chemistry Shandong University, Ji'nan 250100;
3.
Langmuir Center for Colloids and Interfaces, Columbia University, NY 10027, U. S. A

Received Date: 22 December 2000

Fund Project: We wish to thank to the National Natural Science Foundation of China (to grant No. 29903006 and 29973023) and the Visiting Scholar Foundation of Key Laboratory in University of China for financial support.

By using the iterative method in functional theory, an analytic expression of the Poisson-Boltzmann equation (PB eq.), which describes the distribution of the potential of electrical double layer of a spherical micelle, has been carried out under the general potential condition for the first time. The method also can give the radius, the surface potential, and the thickness of the layer.
- Functional analytic theory,
- spherical micelle,
- electrical double layer.
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