Citation: Zong Ping SHAO, Hui DONG, Guo Xing XIONG, Wei Shen YANG. Application of CO₂-TPD in the Synthesis of Composite Oxides from Metal-Organic Precursors[J]. Chinese Chemical Letters, ;2000, 11(6): 561-564. shu

Application of CO₂-TPD in the Synthesis of Composite Oxides from Metal-Organic Precursors

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics Chinese Academy of Sciences, P, O, Box 110, Dalian 116023

Received Date: 21 December 1999
Revised Date: 17 March 2000

Fund Project: The authors gratefully acknowledge financial supports from the National Natural Science Foundation of China (Grant No.59789201), the National Advanced Materials Committee of China (Grant No.715-006-0122) and the Ministry of Science and Technology, China (Grant No.G1999022401).

CO₂-TPD was demonstrated an effective way to investigate the phase formation during pyrolysis for the preparation of composite oxides using metal-organic molecules as precursors. Based on the CO₂-TPD results, it was found that calcination condition had deep effect on the carbonate formation and the minimum firing temperature to acquire pure phase composite oxide. An optimized calcination schedule was then developed.
- CO₂-TPD,
- composite oxide,
- synthesis,
- metal-organic precursors
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