Citation: Guo Fu ZI, Cheng Lie YIN. Asymmetric Trimethylsilylcyanation of Benzaldebyde Catalyzed by Novel Ti(Ⅳ)-Chiral Schiff Base Complexes[J]. Chinese Chemical Letters, ;1997, 8(12): 1013-1014. shu

Asymmetric Trimethylsilylcyanation of Benzaldebyde Catalyzed by Novel Ti(Ⅳ)-Chiral Schiff Base Complexes

Guo Fu ZI ,
Cheng Lie YIN

Department of Chemistry, Beijing Normal University, Beijing, 100875

Received Date: 18 August 1997

Fund Project: This project was supported by the National Natural Science Foundation of China and the Doctor Foundation of State Education Committee of China.

Benzaldehyde has been trimethylsilylcyanated with a catalyst prepared in situ from titanium tetraisopropoxide and chiral Schiff bases.Cyanohydrin is obtained in moderate e.e.values.
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