Citation: Song Lin ZHANG, Yong Min ZHANG. Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles[J]. Chinese Chemical Letters, ;1998, 9(10): 885-887. shu

Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles

Department of Chemistry, Hangzhou University, Hangzhou, 310028

Received Date: 30 March 1998

Fund Project: We are grateful to the National Natural Science Foundation of China (Project No. 294938004 and 29672007) and to the Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, for financial support.

The Se-Si bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with α,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.
- samarium diiodide,
- arylselenotrimethylsilane,
- arylseleno esters,
- arylseleno nitriles
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