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Song Lin ZHANG, Yong Min ZHANG. Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles[J]. Chinese Chemical Letters,
;1998, 9(10): 885-887.
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The Se-Si bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with α,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.
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