Citation: Mei Fang Wu, Zhong Ning CHAN, Jun QIU, Wen Xia TANG, Zhe Ming WANG, Shi Xiong LIU, Jin Ling HUANG. SYNTHESIS AND STRUCTURE OF A 2D SHEET-LIKE COPPER(Ⅱ) COMPLEX WITH BRIDGING PYRIDINE-4-CARBOXYLATE AND TRANS-OXAMIDATE LIGANDS[J]. Chinese Chemical Letters, ;1994, 5(8): 711-712. shu

SYNTHESIS AND STRUCTURE OF A 2D SHEET-LIKE COPPER(Ⅱ) COMPLEX WITH BRIDGING PYRIDINE-4-CARBOXYLATE AND TRANS-OXAMIDATE LIGANDS

1.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008;
2.
Center Laboratory, Fuzhou University, Fuzhou 350002

A complex polymer[Cu₂(oxen)(pic)(H₂O)]_N(ClO₄)·ZnH₂O,where oxen and pic are N,N'-bis(2-aminoethyl)oxamide and pyridine-4-carboxylate,respectively,was synthesized.It crystallizes in the monoclinic space group P2₁/c,with a=10.420(2) Å,b=13.118(2) Å,c=14.863(5) Å,β=93.05(2)°,and z=4.The structure of this complex consists of 2D network of copper(Ⅱ) ions bridged by bis-tridentate oxen in trans-conformation,and by pyridine-4-carboxylate in which the pyridine ring acts as a monodentate group whereas the carboxylate as a tridentate group and bonds to three different copper centres in a novel fashion.The repeating asymmetric unit is a binuclear copper(Ⅱ) fragment with one of the copper centre locating in a lengthening octahedral environment,whereas the other in a distorted tetragonal pyramid geometry.
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