Citation: Xue Song WU, Hong Sui SUN, Yi PAN, Hua Bing CHEN, Xiang Zhen SUN. The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol[J]. Chinese Chemical Letters, ;1999, 10(10): 875-878.
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The reaction of the trialkyl metals (R3M, R=Me, Et; M=Ga, In) with henzo[h]quinolin-10-ol] (HO-BQ) in a 1:1 molar ratio gave intramolecular N coordinated complexes R2M-O-BQ (M=Ga, R=Me 1, Et 2) and (R2In-O-BQ)2 (M=In, R=Et 3,)in 80-90% yield. The molecular structures of complexes 1 and 3 have been established by X-ray crystallography.
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Keywords:
- Metal trialkyls,
- gallium,
- indium,
- MOCVD precursors,
- X-ray crystal structure
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