Citation: Song Lin ZHANG, Feng Shou TIAN, Gong An LI, Yu Lu WANG. Zn/ZrCl₄ System Induced Reductive Cleavage of Se-Se Bond in Diaryl Diselenides:A Novel Method for the Systhesis of Selenoesters[J]. Chinese Chemical Letters, ;2002, 13(1): 9-12. shu

Zn/ZrCl₄ System Induced Reductive Cleavage of Se-Se Bond in Diaryl Diselenides:A Novel Method for the Systhesis of Selenoesters

College of Chemistry and Environmental Science, Henan Normal University Xinxiang 453002

Received Date: 14 May 2001

Fund Project: We are grateful to the Natural Science Foundation of Henan Province (Project No. 004030700), and Youth Science Foundation of Henan Nornial University (Project No. 520458) for financial supports.

The Se-Se bond in diaryl diselenides was reduced by Zn/ZrCl₄ system to produce selenide anions, which react with acyl chlorides or acid anhydrides to afford selenoesters in THF under mild and neutral conditions.
- Diselenides,
- zinc,
- zirconium (IV) chloride,
- selenoesters
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