Citation: Bao Zhong CAI, Lun Tzu LIU, Ru Yu CHEN. STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS[J]. Chinese Chemical Letters, ;1991, 2(7): 531-534. shu

STUDIES ON 1, 2, 3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1, 2, 3-DIAZAPHOSPHOLE WITH ALCOHOLS

Institute of Elemento-Organic Chemistry Nankai University Tianjin 300071

Received Date: 10 May 1991

Fund Project: This project was supported by the National Natural Science Foundation of China and 21th Century Foiindation of Tianjin for Young Scientists.

Rapid addition of alcohols to 1, 2, 3-diazaphosphole 1 easily gave tricoordinated phosphorus compounds, which were sulfurized to tetracoordinated phosphorus compounds.When ethylene glycol and aminoethanol were used separately to react with 1, the tricoordinated phosphorus compounds which formed, rearranged to pentacoordinated phosphorus compounds and the substituents at N₂ affected the rearrangement significantly
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