Citation: Bin ZHAO, Yang Jie WU, Jing Chao TAO, Han Zhen YUAN. SYNTHESES OF NEW NITROGEN-OXYGEN DONOR MACROCYCLES[J]. Chinese Chemical Letters, ;1995, 6(5): 373-376.
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Twelve new nitrogen-oxygen donor macrocycles have been synthesized by condensation of N,N-bis [2-(2-formylphenoxy) ethyl]-4-methylphenylsulfonamide with diamines followed by a one pot reduction of the corresponding Schiff-base derivatives.The 4-methylphenylsulfonyl group can be removed by Na-Hg (6%) in methanol.All of the new aza-crowns were identified by EA,NMR,IR and MS.
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