Citation:
WENG Zhixue, LOU Jianfeng, HUANG Zhiming, PAN Zuren. SUSPENSION-SWELLING GRAFT COPOLYMERIZATION——SYNTHESIS OF ACS RESINS*[J]. Chinese Journal of Polymer Science,
;1993, 11(4): 293-299.
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Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were studied. Highly effective comples dispersing system was chosen and determined, and two-layer protection model was put forward to clarify the stable effect mechanism Varying the swelling time of CPE in AN and St monomer mixture, some results such as grafting effect, particle characteristics, rubber particle morphology and its size distribution,and properties of ACS resins were investigated,thus the optimum swelling time was proposed.
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