Citation:
Wang Yanji, Tang Jing, Li Hexuan. Study on Catalytic Behavior of Hβ Zeolite Modified by Oxides[J]. Chinese Journal of Applied Chemistry,
;1995, 12(6): 21-24.
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The effect of B2O3 and Fe2O3 on the surface acidity and propylene etherification with isopropanol to isopropyl ether has been investigated by XRD, XPS,NH3-TPD, FT-IR and chemisorption. These impregnated oxides played a great role in modifying the total sur-face acid amount and distribution of acid strength. The stronger interaction between oxides and Hβ-Al2O3 enhanced the L acid amount. Meanwhile,the performance of propylene etheri-fication was obviously improved. A good relationship between propylene conversion and sur-face L acid amount was detected.
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Keywords:
- oxide,
- Hβ-zeolite,
- propylene etherification,
- surface acidity
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