Citation: Fu Hai WU, Xue Yi LE, Fen Yun SONG, Liang Nian JI. THE INTRAMOLECULAR STACKING INTERACTION IN TERNARY COMPLEXES FORMED BY AND HETEROAROMATIC N-BASE LIGANDS[J]. Chinese Chemical Letters, ;1996, 7(8): 773-776. shu

THE INTRAMOLECULAR STACKING INTERACTION IN TERNARY COMPLEXES FORMED BY AND HETEROAROMATIC N-BASE LIGANDS

Fu Hai WU ^c ,
Xue Yi LE ^a,b,c ,
Fen Yun SONG ^c ,
Liang Nian JI ^a,b,c

a Department of Chemistry, Zhongshan University, University, Guangzhou 510275;
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008;
c Guangdong Pharmaceutical College

Received Date: 9 October 1995

The stability constants of binary ML²⁺ complexes formed by Zn²⁺ or Cd²⁺ (M²⁺) and isoquinoline or benzimidazole (L) and ternary M (ATP) L^2- complexes containing ATP in addition were determined by potentiometric pH titration in aqueous solution. It has been found that there is an intramolecular stacking interaction between the heteroaromatic N-Base ligands and the base part of ATP in the ternary complexes, this interaction may have relation to the structure of the aromatic rings of the L ligands.
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