Citation: Zhen Ting DU, Xue Gong SHE, Guo Ren YUE, Jun Ying MA, Yang LI, Xin Fu PAN. Enantioselective Synthesis of (+)-Nuciferal, (+)-(E)-Nuciferol and (+)-α-Curcumene by Chiral Hydrogenesterification Reaction[J]. Chinese Chemical Letters, ;2004, 15(12): 1389-1391. shu

Enantioselective Synthesis of (+)-Nuciferal, (+)-(E)-Nuciferol and (+)-α-Curcumene by Chiral Hydrogenesterification Reaction

1.
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000;
2.
Department of Chemistry, Hexi University, Zhangye 734000

Received Date: 22 October 2003

Fund Project: We are grateful to the National Natural Science Foundation of China (No. 20172023) for financial support.

Using chiral hydrogenesterification reaction as the key step, the stereoselective synthesis of (+)-nuciferal 1, (+)-(E)-nuciferol 2 and (+)-α-curcumene 3 has been achieved.
- Nuciferal,
- nuciferol,
- α-curcumene,
- enantioselective synthesis
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15. [15]
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