Citation: Tie Jun WANG, Zhao Hui MA, Mei Yu HUANG, Ying Yan JIANG. ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX[J]. Chinese Chemical Letters, ;1996, 7(1): 47-50. shu

ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N,N'-BIS[2-(BENZIMIDAZOLYLMETHYL)] AMINO FERROUS ACETATE COMPLEX

Institute of Chemistry, Academia Sinica, Beijing, 100080

Received Date: 5 June 1995

Silica immobilized N,N'-bis[-2-(benzimidazolylmethyl)]amino-ferrous acetate complexes (Ⅳ) catalyzed monooxygenation of cyclohexane to cyclohexanol with the turnover number 8.4 (equivalent C%=11.2) under mild conditions.The methylene blue is the most effective electron transfer agent which can also regulate products distribution.The iron content of the polymer-supported complexes,the redox potentials and the concentration of methylene blue greatly affect the activity and selectivity of the complex (Ⅳ).
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