Citation: Wei-ming Zhang, Jin-long Chen, Qun Chen, Ming-yang He, Bing-cai Pan, Quan-xing Zhang. Adsorption of Laterally Interacting 1-Naphthol/1-Naphthyl-Amine Mixtures on Nonpolar Surfaces from Aqueous Solutions[J]. Chinese Journal of Polymer Science, ;2006, 24(1): 73-80. shu

Adsorption of Laterally Interacting 1-Naphthol/1-Naphthyl-Amine Mixtures on Nonpolar Surfaces from Aqueous Solutions

Received Date: 24 January 2005
Revised Date: 25 March 2005

The binary adsorption behavior of 1-naphthol/1-naphthylamine mixtures in water on nonpolar adsorbent Amberlite XAD4 was investigated at 293 K, 303 K and 313 K, respectively. The experimental uptakes of 1-naphthol and 1-naphthylamine in all binary-component systems of different molar ratios were obviously higher than the corresponding uptakes predicted by the extended Langmuir model, assuming no interaction between the adsorbed molecules of the two components. This phenomenon was attributed to the cooperative adsorption effect arising from the hydrogen bonding interaction between 1-naphthol and 1-naphthylamine molecules. A modified extended Langmuir model was proposed to describe the binary adsorption behavior by means of introducing a fitting parameter related with the cooperative adsorption effect of the adsorbates.
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