Citation: Kui Ling DING, Yang Jie Wu, Yang WANG, Li YANG. STUDIES ON THE PROPERTIES OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS Ⅲ TRANSMETALLATION REACTION OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS WITH METALLIC TIN[J]. Chinese Chemical Letters, ;1993, 4(3): 221-224. shu

STUDIES ON THE PROPERTIES OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS Ⅲ TRANSMETALLATION REACTION OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS WITH METALLIC TIN

1.
Department of Chemistry, Zhengzhou University, Zhengzhou 450052;
2.
Lanzhou University, National Applied Laboratory of Organic Chemistry, Lanzhou, 730000

Received Date: 14 September 1992

Fund Project: We are grateful to the National Natural Science Foundation of China and Natural Science Foundation of Henan Province for generous support of this work.

The transmetallation reaction of 4 Schiff base type arylmercury compounds with metallic tin has been carried out in refluxing xylene.It was found that the reaction proceeds in the same manner as that of chloro[2-(phenylazo)phenyl]mercury(Ⅱ)to give dichlorobisaryltin(Ⅳ).The ¹H NMR spectra of the products provide evidence for the presence of N→Sn intramolecular coordination.The formation of dichlorobisaryltin(Ⅳ)as a unique product probably arises from the N→Sn intramolecular coordination which results in the increasing of the stability of the molecule.
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