Citation: WANG Wei, QIU Kunyuan, FENG Xinde. GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*[J]. Chinese Journal of Polymer Science, ;1994, 12(2): 137-144. shu

GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*

Received Date: 20 November 1992

Two copolymers containing p-tolylcarbamoyl pendant group poly (MAMT-co-VAc) and poly(MAMT-co-MA) were synthesized f and the graft copolymerization of AAM onto these two func-tional copolymers films initiated with ceric salt were carried out in aqueous solution for variousperiods at 30℃. The formation of graft copolymer was verified by water absorption, ESCA andSEM photographs. Based on the results of the study of the initiation mechanism of model com-pounds and ceric salt systems, the reaction mechanism of graft copolymerization initiated with ceric salt was proposed.
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