Citation: Ye Feng WANG, Yuan ZHOU, Jia Rui WANG, Lei LIU, Qing Xiang GUO. CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides[J]. Chinese Chemical Letters, ;2006, 17(10): 1283-1286. shu

CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides

Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received Date: 6 March 2006

Fund Project: This research was supported by the NNSFC (No. 20332020, and No. 20472079).

An operationally simple and inexpensive catalyst system was developed for the cross coupling of potassium thiocyanate with aryl iodides by using CuI as catalyst, 1, 10-phenanthroline as ligand, and tetraethylammonium iodide as activator. The procedure is applicable for the synthesis of diverse aryl thiocyanates without any exotic, poisonous reagents.
- Cross coupling reaction,
- CuI,
- aryl thiocyanate,
- aryl iodide,
- 1, 10-phenanthroline
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