Citation: Xiao Ming XIAO, Takeko MATSUMURA-INO UE. ⁹⁹Ru and ¹³C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)[J]. Chinese Chemical Letters, ;1998, 9(8): 765-766. shu

⁹⁹Ru and ¹³C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium(Ⅱ)

Xiao Ming XIAO ¹ ,
Takeko MATSUMURA-INO UE ²

1.
Department of chemistry Hunan Normal University Changsha 410081;
2.
Department of Chemistry Nara University of Education Nara 63O Japan

Received Date: 16 March 1998

¹³C and ⁹⁹Ru-NMR chemical shifts are reported for the ruthenium(Ⅱ) tris complexes of 5-substituted 1,10-phenanthrolines. It has been found that both of them are affected by the substituents on the phenanthrolines in a direction consistent with that expected from the electron withdrawing ability of the substituent.
- NMR spectrum,
- ruthenium(Ⅱ) complex,
- substituent effect
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