Citation: Shui Quan DENG, Hong Hui ZHUANG, Ding Ming WU, Jin Ling BUANG. A NEW TYPE OF CHAIN COMPOUND,STRUCTURE OF TA₄(TE₂)₄TE₄I[J]. Chinese Chemical Letters, ;1993, 4(3): 273-274. shu

A NEW TYPE OF CHAIN COMPOUND,STRUCTURE OF TA₄(TE₂)₄TE₄I

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences and State Key Laboratory of Structure Chemistry, Fuzhou, Fujian 350002

Received Date: 10 August 1992

Ta₄(Te₂)₄Te₄I,Mr=2381.90,Monoclinic,C2/c,a=21.987(2),b=6.153(2),c=19.936(3)Å,β=122.42(14),V=2276.7Å³,z=4,Dm=6.8(5)g/cm³,Dc=6.95g/cm³,λ(Mok_α)=0.71073Å,μ=354.0cm^-1,F(000)=3876,T=296(1)k,R=5.3%,Rw=6.8%,for 1118 unique observed reflections(1>3σ(Ⅰ)).The structure is composed of [Ta₄(Te₂)₄Te₄I]_∞ chains,which are formed by the four-nuclear butterfly cluster units "Ta₄(Te₂)₄Te₄"with the Ⅰ atoms as the bridging atoms between different cluster units.
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