Citation: LIU Bin, DONG Heng, SUN Ji-Hong. Effect of the additives PVP and MTS on structural properties and synthesis mechanism of Beta zeolite[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(4): 468-474. shu

Effect of the additives PVP and MTS on structural properties and synthesis mechanism of Beta zeolite

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: SUN Ji-Hong, jhsun@bjut.edu.cn
Received Date: 24 February 2017
Revised Date: 7 March 2017

Fund Project: the National Natural Science Foundation of China 21576005the National Natural Science Foundation of China 21276005the Beijing Municipal Natural Science Foundation 2152005

Figures(9)

Beta zeolites were successfully synthesized via hydrothermal method using sodium aluminate as aluminium source, silica sol (Ludox) as silicon source and TEAOH as template, respectively. The effects of different additives polyvinyl pyrrolidone (PVP) and Methyltriethoxysilane (MTS) on their structural properties and synthesis mechanism were investigated in detail by various characterizations, such as XRD, TEM, BET, ICP, ²⁹Si-NMR and NH₃-TPD method. Also, their catalytic performances were evaluated through catalytic cracking of cumene. The results showed that the beta zeolite obtained in the PVP-added system presented a better crystallinity, higher Si/Al molar ratio (25.68), and larger surface area (772 m²/g). Comparably, the MTS-effected samples revealed a larger surface area (657 m²/g), higher Si/Al molar ratio (25.76), but lower crystallinity and smaller particle sizes (around 160-320 nm). Moreover, both of them exhibited a good catalytic activity for cumene cracking due to the existences of abundant and strong acid content.
- PVP,
- MTS,
- Beta zeolite,
- catalytic cracking,
- structural characterization,
- hydrothermal synthesis
1. [1]
  WADLINGER R L, KERR G T, ROSINSKI E J. Catalytic composition of a crystalline zeolite:US, 3308069[P]. 1967-03-07.
2. [2]
  BELLUSSI G, PAZZUCONI G, PEREGO C, GIROTTI G, TERZONI G. Liquid-phase alkylation of benzene with light olefinscatalyzed by β-Zeolites[J]. J Catal, 1995,157(1):227-234. doi: 10.1006/jcat.1995.1283
3. [3]
  ARRIBAS M A, MARTINEZ A. Simultaneous isomerization of n-heptane and saturation of benzene over Pt/Beta catalysts:The influence of zeolite crystal size on product selectivity and sulfur resistance[J]. Catal Today, 2001,65(2/4):117-122.
4. [4]
  DING L, ZHENG Y, HONG Y, RING Z. Effect of particle size on the hydrothermal stability of zeolite Beta[J]. Microporous Mesoporous Mater, 2007,101(3):432-439. doi: 10.1016/j.micromeso.2006.12.008
5. [5]
  SERRANO D P, AGUADO J, ESCOLA J M, RODRIGUEZ J M, PERAL A. Hierarchical zeolites with enhanced textural and catalytic properties synthesized from organofunctionalized seeds[J]. Chem Mater, 2006,18(10):2462-2464. doi: 10.1021/cm060080r
6. [6]
  AGUADO J, SERRANO D P, RODRIGUEZ J M. Zeolite Beta with hierarchical porosity prepared from arganofuctionalized seed[J]. Microporous Mesoporous Mater, 2008,115(3):504-513. doi: 10.1016/j.micromeso.2008.02.026
7. [7]
  WANG Run-wei, LIN Sen, MENG Xiang-ju, LI Bin-song, JIANG Da-zhen, XIAO Feng-shou, QIU Shi-lun. Influence of catalysts particle size on alkylation of isobutane with butene over Hβ zeolites[J]. Chem J Chin Univ, 2003,24(2):205-207.
8. [8]
  MOLLER K, YILMAZ B, JACUBINAS R M, MULLER U, BEIN T. One-step synthesis of hierarchical zeolite beta via network formation of uniform nanocrystals[J]. J Am Chem Soc, 2011,133(14):5284-5295. doi: 10.1021/ja108698s
9. [9]
  DING L, ZHENG Y, ZHANG Z, RING Z, CHEN J. Effect of agitation on the synthesis of zeolite beta and its synthesis mechanism in absence of alkali cations[J]. Microporous Mesoporous Mater, 2006,94(1/3):1-8.
10. [10]
  SHAN Zhi-chao, LIU Si-yu, LI Cai-jin, ZHU Long-feng, MENG Xiang-ju, XIAO Feng-shou. High-temperature synthesis of zeolite Y[J]. Acta Phys Chim Sin, 2011,27(4):959-964.
11. [11]
  VUONG G T, DO T O. A new route for the synthesis of uniform nanozeolites with hydrophobic external surface in organic solvent medium[J]. J Am Chem Soc, 2007,129(13):3810-3811. doi: 10.1021/ja069058p
12. [12]
  VAN BOKHOVEN J A, AM V D E, KONINGSBERGER D C. Three-coordinate aluminum in zeolites observed with in situ X-Ray absorption near-edge spectroscopy at the Al K-edge:Flexibility of aluminum coordinations in zeolites[J]. J Am Chem Soc, 2003,125(24):7435-7442. doi: 10.1021/ja0292905
13. [13]
  XU Ru-ren, PANG Wen-qin, YU Ji-hong, HUO Qi-sheng, CHEN Jie-sheng. Chemistry-Zeolites and Porous Materials[M]. Beijing:Science Press, 2004:74-76.
14. [14]
  YARIPOUR F, SHARIATINIA Z, SAHEBDELFAR S, LRANDOUKHT A. Effect of boron incorporation on the structure, products selectivities and lifetime of H-ZSM-5 nanocatalyst designed for application in methanol-to-olefins (MTO) reaction[J]. Microporous Mesoporous Mater, 2015,203:41-53. doi: 10.1016/j.micromeso.2014.10.024
15. [15]
  ZHU Jin-hong, LIU Jing, ZHAO Wen-jiang, WANG Xiang-sheng, LIU Xiu-mei, BAO Xin-he. Synthesis and characterization of Al-MSU-S mesoporous and meso-microporous molecular sieves and their catalytic performance[J]. Chin J catal, 2004,25(9):741-747.
16. [16]
  KUMARAN G M, GARG S, SONI K, KUMAR M, GUPTA J K, SHARMA L D, RAMA RAO K S, MURALI DHAR G. Synthesis and characterization of acidic properties of Al-SBA-15 materials with varing Si/Al ratios[J]. Microporous Mesoporous Mater, 2008,114(1/3):103-109.
1. [1]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
2. [2]
  Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
3. [3]
  Ping LI , Geng TAN , Xin HUANG , Fuxing SUN , Jiangtao JIA , Guangshan ZHU , Jia LIU , Jiyang LI . Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020
4. [4]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
5. [5]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-0. doi: 10.3866/PKU.WHXB202406012
6. [6]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
7. [7]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
8. [8]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
9. [9]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
10. [10]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
11. [11]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
12. [12]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
13. [13]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
14. [14]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
15. [15]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
16. [16]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
17. [17]
  Pan Li , Huguo Shen , Cong Hua , Jinjie Fang , Xiangying Chi , Quan Jiang , Zichen Feng , Ye Kang , Bin Zheng . Synthesis and Characterization of an Aggregation-Induced Emission-Active Organic Cage Molecule: A Proposed Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(11): 337-345. doi: 10.12461/PKU.DXHX202502083
18. [18]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
19. [19]
  Chunru Zhao , Yi Liu , Shilong Li , Xiang Wu , Jinghai Liu . PVP decorated H_3.78V₆O₁₃ microspheres assembled by nanosheets for aqueous zinc ion batteries at variable work temperature. Chinese Chemical Letters, 2025, 36(6): 110185-. doi: 10.1016/j.cclet.2024.110185
20. [20]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(2432)
HTML views(841)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142